飽和脂肪酸エステルの熱分解 (第2報) : 酢酸メチルの熱分解

概要

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Methyl acetate was pyrolyzed at 450, 500, 550, 600, 650, 700, 750 and 800°C, respectively, whose pyrolyzates were analyzed. This was difficult to decompose in the lower temperature range with the decomposition of only 44% at 650°C, while, in the higher range, the reaction advanced rapidly withh a maximum of more than 90% at 800°C. The principal products in the temperature range higher than 700°C were carbon monoxide and methane, and besides, considerable quantity of water, carbonn dioxide, acetone, methanol, acetic acid and formaldehyde were produced. Among these products, carbon monoxide, methane and formaldehyde increased in the quantity with rise of the pyrolysis temperature, whereas, water, acetone and methanol were produced in much quantity in the range up to 650°C, and they decreased at higher temperature than that.
社団法人日本油化学会の論文