高分子担持試薬ならびに触媒を用いる反応 : その特異な挙動と活用

概要

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An increasing number of papers concerning polymer-anchored reagents and catalysts have been appeared during the past decade due to the specific advantages for organic synthesis.<BR>This article describes characteristic features of insoluble resins as supports, reagents or catalysts; this includes the high-dilution or pseudodilution effect, stabilization of reagents and catalysts, site-site isolations, and site-site interactions. Subsequently, applications to organic reactions of these reagents, such as asymmetric synthesis on polymer backbone, cyclization reaction, capture of reactive intermediates, and phase-transfer reactions are also included. Merits and limitations using polymeric reagents and catalysts are discussed.
社団法人有機合成化学協会の論文