塗料原料とする漁油塩素化物の製造に関する研究-V : 塩素の通気速度について

概要

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Relations among the rate of chlorine aeration, yields of the products and agitation of reaction mixtures were studied under the assumption that the apparent chlorination velocity of fish oil is proportional to yield velocity of the products. As the apparent velocity of chlorination proved to agree with equation (1) at the later, aeration of chlorine is necessitated to be vigorous at first and gentle later so that little excess of chlorine may get out of the reaction liquid. So far as the present experiment is concerned, agitation of reaction liquid is not effective enough to accelerate the chlorination probably for the reason that the real reaction occurs only in the boundary film between chlorine and oil, in which no convection goes on.
公益社団法人日本水産学会の論文