3.2 高分子多成分系のスピノーダル分解
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概要
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Small-angle neutron scattering (SANS) studies on the miscibility, critical phenomena and phase transitions by spinodal decomposition of polymer mixtures are reviewed. SANS with the “deuterium labeling technique” is a powerful technique to study one-phase state of polymer mixtures. Interaction parameters, phase diagrams, critical exponents, etc. can be obtained for the one-phase mixtures of deuterated and undeuterated polymers. Time-resolved SANS is extremely useful to study early stage of spinodal decomposition and local structure such as interphases and thermal concentration fluctuations in the coexisting domains in the later stage of spinodal decomposition of polymer mixtures.
- 日本結晶学会の論文
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