Prediction of solid-liquid equilibria from vapor-liquid equilibrium data using the solution of groups model.
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概要
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A new algorithm, based on the solution of groups model, is proposed to predict liquid-phase activity coefficients. This method is not an extension of the so-called ASOG model but is rather a simple application of the solution of groups model. The molecular activity coefficients of solid-liquid equilibria were calculated directly from the correlated vapor-liquid equilibria of the other component pairs, which consisted of the same group as solid-liquid equilibria. This method was successfully used for predicting the solid-liquid equilibria of binary systems which included naphthalene as one component.
- 公益社団法人 化学工学会の論文
著者
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Hoshino Daisuke
Department Of Cancer Cell Research Institute Of Medical Science University Of Tokyo
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Nagahama Kunio
Department Of Applied Chemistry Tokyo Metropolitan University
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HIRATA MITSUHO
Department of Chemical Engineering, Faculty of Engineering, Tokyo Metropolitan University
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UNNO YOSHIKI
Department of Industrial Chemistry, Tokyo Metropolitan University
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