Regio- and Enantioselective Allylic Substitution with Less Active N- or O-Nucleophiles Catalyzed by Iridium-Complex of Bis(oxazolinyl)pyridine
スポンサーリンク
概要
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The utility of hydroxylamines as nitrogen nucleophiles was investigated in the iridium-catalyzed regio- and enantioselective allylic substitution. Allylic substitution with hydroxylamines proceeded with good enantioselectivities by using the iridium-complex of bis(oxazolinyl)pyridine ligand. The good regio- and enantioselectivities were also achieved in the reaction with alkylamines, p-anisidine, and 4-methoxyphenol.
著者
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Takemoto Yoshiji
Graduate School Of Pharmaceutical Sciences Kyoto Univ.
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MIYABE Hideto
Graduate School of Pharmaceutical Sciences, Kyoto University
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Miyabe Hideto
Graduate School Of Pharmaceutical Sciences Kyoto University
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Moriyama Katsuhiko
Graduate School of Pharmaceutical Sciences, Kyoto University
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Takemoto Yoshiji
Graduate School of Pharmaceutical Sciences, Kyoto University
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