Phase Equilibria in FeS–XS and MnS–XS (X=Ti, Nb and V) Systems
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概要
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The phase equilibria in the FeS–XS and MnS–XS (X: Ti, Nb and V) pseudo-binary systems were investigated by using an X-ray diffraction and electron probe micro analyzer. In the FeS–TiS and FeS–VS systems, a mono-sulfide with the NiAs structure form a complete solid solution, while two-phase separation of the mono-sulfide with the NiAs structure is observed in the FeS–NbS system. In all MnS–XS systems, two-phase region of a Mn-rich mono-sulfide and X-rich mono-sulfide exists widely. Solubility of each elements in the Mn-rich mono-sulfide and X-rich mono-sulfide is small, except that of Mn in Nb-rich mono-sulfide.
著者
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Oikawa Katsunari
Department of Materials Science, Graduate School of Engineering, Tohoku University
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Sasaki Tomoyuki
Department of Materials Science, Graduate School of Engineering, Tohoku University
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Mitsui Hajime
Department of Materials Science, Graduate School of Engineering, Tohoku University
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Ishida Kiyohito
Department of Materials Science, Graduate School of Engineering, Tohoku University
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