Electrochemical Properties of A Dual Porphyrin System with Marked Affinity toward DABCO
スポンサーリンク
概要
- 論文の詳細を見る
Electrochemical characterization was made of a dual porphyrin system built on a calix[4]arene spacer and that of a porphyrin monomer. The porphyrin dimer showed marked affinity toward 1,4-diazobicyclo[2.2.2]octane (DABCO) such as that of molecular tweezers and reacted strongly with large interactions in the ground state as indicated by electrochemical behavior. Compared to the monomeric porphyrin, the initial oxidation potentials for this dimer were significantly reduced and reoxidation occurred in two distinct redox steps.
- 日本油化学会の論文
著者
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ARIMURA Takashi
Nanotechnology Research Institute, AIST
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Tachiya Masanori
AIST Fellow
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Tachiya Masanori
National Inst. Advanced Industrial Sci. And Technol. Tsukuba Jpn
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Kumamoto Satoshi
Nanotechnology Res. Inst. Aist
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TACHIYA M.
Fellow, National Institute of Advanced Industrial Science and Technology (AIST)
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ARIMURA Takashi
Nanotechnology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
関連論文
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- Molecular Complexation of Arenediazonium Ions by a Calix[4]arene Possessing Two Ester Groups : Molecular Tweezers
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