Sodium-23 NMR Studies of Sodium Ion Ensembles with a 1,3-Alternate-Shaped Calix[4]arene
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概要
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Sodium-23 NMR longitudinal magnetization recovery (L.M.R.) study has been carried out to clarify the sodium ion exchange in ensembles with 1,3-alternate-shaped calix[4]arene 1 for the first time. The line width υ1/2 of a sharp singlet for NaClO4 in the absence of 1 is 65 Hz: upon addition of 1 a singlet peak was broadened to 1100 Hz (υ1/2). The life times (τ) of Na+ were estimated to be (20-3.8)×10-3 s for τA and (5.0-2.0)×10-3 s for τB, by the simulations of sodium-23 NMR L.M.R. curves. The life times of 1-Na+ Ensemble are larger than those for 18-crown-6. This implies that Na+ cation is bound deeply in the cavity formed by two OCH2CO groups of 1, the complex being classified as a “nest-in-type”.
- 日本油化学会の論文
著者
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ARIMURA Takashi
Nanotechnology Research Institute, AIST
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NISHIOKA Takuya
Nanotechnology Research Institute, AIST
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Yamaguchi Tomohiko
Nanotechnology Res. Inst. Aist
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Kumamoto Satoshi
Nanotechnology Res. Inst. Aist
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Tsuchiya Youichi
Nanotechnology Laboratory Institute Of Systems Information Technologies And Nanotechnologies (isit)
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TACHIYA M.
Fellow, National Institute of Advanced Industrial Science and Technology (AIST)
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Nishioka Takuya
National Institute Of Advanced Industrial Science And Technology (aist)
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