Photophysical and Electrochemical Properties of Novel Symmetrical and Unsymmetrical 1,4,5,8-naphthalenetetracarboxydiimide Derivatives
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概要
- 論文の詳細を見る
A series of symmetrical and unsymmetrical 1,4,5,8-naphthalenetetracarboxydiimide (NDIM) derivatives were characterized by UV-visible and fluorescence spectral analyses in order to understand the relationships between their structures and physical properties. The UV-visible spectral analyses showed the intermolecular interactions on phenyl group of 3,3-diphenylpropyl derivatives, and the fluorescence spectra suggested the weak intermolecular interactions for 2,5-di-tert-butylphenyl derivatives. These results revealed that 3,5-di-tert-butylphenyl group is one of the best substituents for disturbing the intermolecular interaction. The redox potentials of reduction for NDIM derivatives were slightly shifted to the negative region by the introduction of electron-donating substituents.
- 日本油化学会の論文
- 2002-06-01
著者
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MURATA Shigeo
National Institute of Materials and Chemical Research (NIMC)
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SUGA Yasuhiro
National Instiufe of Materials and Chemical Research, COE laboratory
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ARIMURA Takashi
National Instiufe of Materials and Chemical Research, COE laboratory
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NISHIOKA Takuya
National Instiufe of Materials and Chemical Research, COE laboratory
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Murata S
National Institute Of Advanced Industrial Science And Technology (aist)
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Suga Yasuhiro
Department Of Applied Chemistry Nagoya Institute Of Technology
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TACHIYA M.
National Institute of Advanced Industrial Science and Technology (AIST)
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Tachiya Masanori
AIST Fellow
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Tachiya Masanori
National Inst. Advanced Industrial Sci. And Technol. Tsukuba Jpn
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Nishioka Takuya
National Institute Of Advanced Industrial Science And Technology (aist)
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MURATA Shigeo
National Institute of Advanced Industrial Science and Technology (AIST)
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ARIMURA Takashi
National Institute of Advanced Industrial Science and Technology (AIST)
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Suga Yasuhiro
National Institute of Advanced Industrial Science and Technology (AIST)
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