NADH Model Reaction: Asymmetric Reduction of Nonactivated Carbonyl Compounds with N-Anionized Hantzsch Ester
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概要
- 論文の詳細を見る
As model compounds for NADH coenzymes, three chiral Hantzsch ester-type dihydropyridines were prepared. By their use and 2, 6-dimethyl-3, 5-dicarbo-(-)-menthoxy-l, 4-dihydropyridine that had already been prepared, asymmetric reductions of unactivated prochiral ketones were conducted under the action of alkali metal derivatives at room temperature in a nonpolar solvent, and the alcohol product were obtained in a 36-80% chemical yield and 30-60% enantiomeric excess.
- 社団法人 日本農芸化学会の論文
著者
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Baba Naomichi
Institute For Chemical Research Kyoto University
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Oda Junichi
Institute For Chemical Research Kyoto University
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WATANABE Motoshi
Institute for Chemical Research, Kyoto University
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FUSHIMI Makoto
Institute for Chemical Research, Kyoto University
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INOUYE Yuzo
Institute for Chemical Research, Kyoto University
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