One-, two-dimensional silver(I) coordination polymer with poly(benzylsulfanyl)benzene and photo-induced property

スポンサーリンク

概要

• 論文の詳細を見る

• 本文データの一部は、CiNiiから複製したものである。Threesilver(I) complexes [Ag_2(3bsb)_2(ClO_4)_2] (1) (3bsb; 1,3,5-tris(benzylsulfanyl)benzene), [Ag(4bsb)](ClO_4) (2) (4bsb; l,2,4,5-tetrakis(benzylsulfanyl)benzene) and [Ag_2(6bsb)(C_2F_5COO)](C_2F_5COO)(toluene)_2 (3) (6bsb; hexakis(benzylsulfanyl)benzene) have been prepared and their molecular structures were determined by X-ray crystallography. In 1, the silver ion prefers a tetrahedral coordination geometry and produces a two-dimensional sheet structure. Irradiation of this complex 1 with UV light changes its color from white to red; Heat makes the irradiated sample revert back to white. However, only 3bsb has no characteristic like this photochromism. Complex 2 formed linear chain structure consist of Ag-S in the silver coordination polymer. On the other hand complex 3 have zigzag chain structure consist of silver ions with trigonal coordination geometry. However, the latter two complexes have no indicated photochromism such as complex 1.

• 近畿大学の論文
• 2003-02-28

著者

• Suenaga Yusaku

  近畿大学

• Sugimoto Takeshi

  近畿大学

• Kuroda-Sowa Takayoshi

  近畿大学

• Maekawa Masahiko

  近畿大学理工学総合研究所

• Munakata Megumu

  近畿大学

• Suenaga Yusaku

  Kinki Univ. Osaka Jpn

• Munakata Megumu

  Department Of Chemistry School Of Science And Engineering Kinki University

• Higashino K

  Department Of Chemistry Kinki University

• Maekawa Masahiko

  Department Of Chemistry School Of Science And Engineering Kinki University

• Maekawa M

  Research Institute For Science And Technology Kinki University

• Maekawa Masahiko

  School Of Science And Engineering Kinki University

• Munakata M

  Department Of Chemistry School Of Science And Engineering Kinki University

• Konaka Hisashi

  近畿大学

• Miyako Emi

  近畿大学

• Konaka H

  Department Of Chemistry Kinki University

• Kuroda-Sowa Takayoshi

  Department of Chemistry, Faculty of Engineering, Gifu University

関連論文

• Benzopolythia compounds and di-nuclear silver(I) complex with tribenzo-1,4,5,8,9,12-hexathiatriphenylene as new electron donor ligand : synthesis, crystal structure and properties
• Syntheses, Crystal Structure, and Magnetic Properties of Mn_ Single-Molecule Magnets with Naphthalenecarboxylate Bridges, [Mn_O_(O_2CC_H_7)_(H_2O)_4] and Their Tetraphenyl-phosphonium Salts
• Dye-sensitized Solar Cells with Halide-bridged Mixed-valence Cu(I)-Cu(II) Coordination Polymers with Hexamethylenedithiocarbamate Ligand
• Solvent-Dependent Formation of Di-and Trinuclear Rhodium and Iridium Complexes Bridged by N,N'-Donor Ligands
• Syntheses and Crystal Structures of Novel Di- and Trinuclear Rhodium Complexes Bridged by Pyrazine
• A Novel Mn_ Single-molecule Magnet with a μ_3-Methanesulfonate Bridge
• A Chemical Modification of a Mn_ Single-Molecule Magnet by Replacing Carboxylate Anions with Diphenylphosphate Anions
• Columnar Structures Formed by Dimeric Fe^ Schiff Base Complex : Twisted-Overlap Salophen Platforms and Ferromagnetic Interaction
• Effects of Metal Doping on the Spin-Crossover Properties of an Iron(II) Complex with Extended π-Conjugated Schiff-Base Ligand Having an N_4O_2 Donor Set
• Abrupt Spin Transitions and LIESST Effects Observed in Fe^ Spin-crossover Complexes with Extended π-Conjugated Schiff-base Ligands Having N_4O_2 Donor Sets
• 2-D silver(I) coordination polymer with octakis (benzylsulfany1) naphthalene and twisted naphthalene structure
• Tris (solvent) iridium complex supported by the η^5-penta-methylcyclopentadienyl ligand. Refinement of [Ir (η^5-C_5Me_5)(Me_2CO)_2(H_2O)] (BF_4)_2
• One-, two-dimensional silver(I) coordination polymer with poly(benzylsulfanyl)benzene and photo-induced property
• Crystal Structure of 1:1 Donor-Acceptor Complex between 9,10-Benzophenanthrene and 2,3,5,6-Tetrafluoro-1,4-benzoquinone
• Crystla Structure of η^5-Pentamethylcyclopentadienyl-η^6-toluene Rhodium Tetrafluoroborate, [Rh(Cp*)(η^6-C_6H_5Me)](BF_4)_2(Cp*=η^5-C_5Me_5)
• δ*_-π_L Odd Electron Delocalization onto Aromatic Bridging Ligands in a Paramagnetic Dirhodium Complex and Intermolecular π-Stack Interaction in Crystal
• Syntheses, Structures, and Magnetic Properties of Di-μ_3-Chloride-Bridged Tripalladium Compounds, [Pd_3(μ_3-Cl)_2(HqnS)_6]Cl_2 (HqnS = Quinoline-2(1H)-thione) and [Pd_3(μ_3-Cl)_2(Et_2dtc)_2(PPh_3)_2]・C_6H_6 (Et_2dtc = N, N'-Diethyldithiocarbamate)
• Crystal structure of 9,10-bis(phenylethynyl)anthracene
• Unsymmetrical Oxygenation Products of [Pd(mnt)_2]^ : Syntheses and Crystal Structures of (Bu_4N)_2[Pd(mnt){O_2S_2C_2(CN)_2}] and One-Dimensional Coordination Polymer (Bu_4N)_2[AgPd(mnt){O_2S_2C_2(CN)_2}]_2(mnt=1,2-Dicyano-1,2-ethylenedithiolato)
• Crystal structure of 3,6-bis(dimethylamino)acridine hydroperchloride (acridine orange・HClO_4)
• Crystal stucture of 3,6-bis(dimethylamino)acridine hydroperchloride(acridine orange・HClO4)
• A Novel Two-Dimensional Copper(I) Coordination Polymer with Bridging TTF: Crystal Structure of [Cu(dmtpn)_2(TTF)_](ClO_4)(dmtpn:2,5-dimethylterephthalonitrile)
• Crystal Structure of Tetranuclear Palladium Complex Bridged by Bis(diphenylphosphino)methane, [Pd_4(μ-dppm)_4(μ-Cl)_2](ClO_4)_2・bpe
• Comparative X-Ray Studies of a Copper(I) Coordination Polymer with 1, 2, 4, 5-Tetramethylmercaptobenzene (tmmb), [(CuX)_2(tmmb)]n(X=Br, I)
• Crystal Structure of Dinuclear Copper(I) Complex with 1, 2, 4, 5-Tetramethylmercaptobenzene, [Cu(tmmb)I]_2
• A Novel 3-D Open Coordination Polymeric Network Assembled from Silver(I) and 4,5-Bis(cyanoethylsulfanyl)-1,3-dithiole-2-thione with S…S Contacts
• Benzopolythia Compounds and Dinuclear Silver(I) Complex with Tribenzo-1,4,5,8,9,12-hexathiatriphenylene as New Electron Donor Ligand: Synthesis, Crystal Structure and Properties
• Crystal Structure of Bis(diphenylphosphino)methane Dipalladium(I)Nitrate Complex, [Pd_2(μ-dppm)_2(NO_3)_2]
• Synthesis and crystal structure of nickel(0) dicarbonyl complex with 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole. [Ni(adpt)(CO)_2]_2・(adpt)_2(thf)
• Redetermination of Crystal Structure of Bispotassium (μ-chloro)(bischloro)copper(I) K_2CuCl_3 with Infinite Chains
• Crystal Structure of Bis{cis-bis(diphenylphosphino)ethylene}palladium(0) Acetone Solvate
• Synthesis and Crystal Structure of Bis(diphenylphosphino)methane Dipalladium(I) Complex with 2-Vinylpyridine (vpy). [Pd_2(μ-dppm)_2(vpy)Cl]ClO_4
• Three-fold Interpenetrating Diamondoid Frameworks with π-π Stacking of Alternate Coordinated and Uncoordinated Ligands : Crystal Structures of Copper (I) Coordination Compounds, [Cu (DMTPN) _2] X (DMTPN) (thf) (DMTPN=2, 5-Dimethylterephthalonitrile ; X=BF
• Synthesis and Conducting Properties of a New Mixed-valence Cu(I)-Cu(II) 1-D Coordination Polymer Bridged by Morpholine Dithiocarbamate
• Preparation and Structure of syn- and anti-Bis(μ-thioacetato-κ^2S)bis[bis(dithioacetato-κS:κS')-iridium(III)]
• Synthesis and Crystal Structure of Nickel(0) Dicarbonyl Complex with 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazol.[Ni(adpt)(CO)2]2・(adpt)2(thf)
• Synthesis of a New Mixed-valence Decanuclear Cu(I)-Cu(II) Cluster with a Hexamethylene Dithiocarbamate Ligand
• Synthesis and Crystal Structure of Bis(diphenylphosphino)methane Dipalladium(1) Complex with 2-Vinylpyridine(vpy).〔Pd2(μ-dppm)2(vpy)Cl〕ClO4

もっと見る 閉じる

スポンサーリンク