Benzopolythia compounds and di-nuclear silver(I) complex with tribenzo-1,4,5,8,9,12-hexathiatriphenylene as new electron donor ligand : synthesis, crystal structure and properties
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概要
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Benzopolythia compounds, tribenzo-1,4,5,8,9,12-hexathiatriphenylene (btt), dibenzo-1,4,5,8-tetrathia-anthracene (bta), dibenzo-1,4,5,8-tetrathia-9,10-hydroxy anthracene (bthq), tetra(1,4-dithianaphtho)[a,c,f,h]naphthalene (tdnn) and tetrabenzo-2,2',3,3'5,5',6,6'-octathiabiphenyl (btb) have been synthesized in high yields by the reaction of the thiolate anion of the o-benzenedithiol with the corresponding fluoro-substituted aromatic compounds in the presence of anhydrous K_2CO_3. X-ray analyses of the molecular structures of btt, bta and bthq show a stable chair-shaped conformation with interplanar angles between the phenyl rings and center benzene ring in the range of 132-143° for btt, 125.4° for bta and 131-136° for bthq. The silver(I) complex with btt has been prepared and its molecular structure determined by X-ray crystallography which gives a novel di-nuclear silver(I) complex.
- 2002-02-28
著者
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Suenaga Yusaku
近畿大学
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Sugimoto Takeshi
近畿大学
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Katoh Kazuo
近畿大学
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Higashino Kenji
近畿大学
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Murakami Tomomi
近畿大学
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Shimamaru Yusuke
近畿大学
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Kuroda-Sowa Takayoshi
近畿大学
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Maekawa Masahiko
近畿大学理工学総合研究所
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Munakata Megumu
近畿大学
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Suenaga Yusaku
Kinki Univ. Osaka Jpn
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Munakata Megumu
Department Of Chemistry School Of Science And Engineering Kinki University
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Murakami T
近畿大学
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Higashino K
Department Of Chemistry Kinki University
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Shimamaru Y
近畿大学
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Maekawa Masahiko
Department Of Chemistry School Of Science And Engineering Kinki University
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Maekawa M
Research Institute For Science And Technology Kinki University
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Maekawa Masahiko
School Of Science And Engineering Kinki University
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Munakata M
Department Of Chemistry School Of Science And Engineering Kinki University
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Konaka H
Department Of Chemistry Kinki University
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Kuroda-Sowa Takayoshi
Department of Chemistry, Faculty of Engineering, Gifu University
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