2-D silver(I) coordination polymer with octakis (benzylsulfany1) naphthalene and twisted naphthalene structure

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概要

• 論文の詳細を見る

• 本文データの一部は、CiNiiから複製したものである。The silver(I) complexes of octakis(benzylsulfanyl)naphthalene (obsn), [Ag_4(obsn)(C_2F_5COO) 4_]_2 0.7(CH_2Cl_2) 1 and octakis(phenylsulfanyl)naphthalene (ophn), [Ag_6(ophn)(C_2F_5COO)_6(H_2O)_2] 2 have been prepared and these molecular structure were determined by X-ray crystallography. In 1, the silver ion prefers tetrahedral coordination geometry comprised of two S atoms from the obsn molecules and the two O atoms from the counter anion then producing two-dimensional sheet structure. Interestingly, the naphthalene ring in the complex has large deviations from planarity and end-to-end twists on the order of 32°. On the other hand six sulfur atom of ophn coordinate with silver(I) ion and naphthalene ring of complex 2 has almost planar structure.

• 近畿大学の論文
• 2006-02-28

著者

• Maekawa Masahiko

  Research Institute for Science and Technology, Kinki University

• Suenaga Yusaku

  Kinki Univ. Osaka Jpn

• Munakata Megumu

  Department Of Chemistry School Of Science And Engineering Kinki University

• Higashino K

  Department Of Chemistry Kinki University

• Maekawa Masahiko

  Department Of Chemistry School Of Science And Engineering Kinki University

• Maekawa Masahiko

  Research Institute For Bioresources Okayama University

• Maekawa M

  Research Institute For Science And Technology Kinki University

• Maekawa Masahiko

  School Of Science And Engineering Kinki University

• Munakata M

  Department Of Chemistry School Of Science And Engineering Kinki University

• Suenaga Yusaku

  Department of Chemistry, Kinki University

• Ueda Atsuyoshi

  Department of Chemistry, Kinki University

• Konaka Hisashi

  Department of Chemistry, Kinki University

• Ueda Atsuyoshi

  Department Of Chemistry Kinki University

• Konaka H

  Department Of Chemistry Kinki University

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