Catalytic Hypervalent Iodine Oxidation of p-Dialkoxybenzenes to p-Quinones Using 4-Iodophenoxyacetic Acid and Oxone^[○!R]
スポンサーリンク
概要
- 論文の詳細を見る
A catalytic hypervalent iodine oxidation of p-dialkoxybenzenes using 4-iodophenoxyacetic acid (1) and 2KHSO_5・KHSO_4・K_2SO_4 (Oxone^[○!R]) was developed. Reaction of p-dialkoxybenzenes (2) with a catalytic amount of 1 in the presence of Oxone^[○!R] as a co-oxidant in 2,2,2-trifluoroethanol-water (1:2) gave the corresponding p-quinones (3) in excellent yields without purification. This procedure was applied to synthesis of blattellaquinone (9), the sex pheromone of the German cockroach, Blattella germanica.
- 公益社団法人日本薬学会の論文
- 2008-11-01
著者
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Tian Yuan
Graduate School Of Medicine And Pharmaceutical Sciences University Of Toyama
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YAKURA Takayuki
Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
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YAMAUCHI Yu
Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
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OMOTO Masanori
Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
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Yamauchi Yu
Graduate School Of Medicine And Pharmaceutical Sciences University Of Toyama
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Omoto Masanori
Graduate School Of Medicine And Pharmaceutical Sciences University Of Toyama
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Yakura Takayuki
Graduate School Of Medicine And Pharmaceutical Sciences Univ. Of Toyama
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