Dirhodium(II)-Catalyzed C-H Amination Reaction of (S)-3-(tert-Butyldimethylsilyloxy)-2-methylpropyl Carbamate : A Facile Preparation of Optically Active Monoprotected 2-Amino-2-methyl-1,3-propanediol
スポンサーリンク
概要
- 論文の詳細を見る
Dirhodium(II)-catalyzed C-H amination reaction of (S)-3-(tert-butyldimethylsilyloxy)-2-methylpropyl carbamate, which was easily prepared from methyl (S)-2-methyl-3-hydroxypropanoate, proceeded more smoothly than those of their 2-(methoxycarbonyl)propyl derivative to give the corresponding oxazolidinone in excellent yield. The resulting oxazolidinone was converted efficiently into both (R)-monoprotected and (S)-monoprotected 2-amino-2-methyl-1,3-propanediols.
- 公益社団法人日本薬学会の論文
- 2007-09-01
著者
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Ishida Chisaki
Graduate School Of Medicine And Pharmaceutical Sciences University Of Toyama
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Yoshimoto Yuya
Graduate School Of Medicine And Pharmaceutical Sciences University Of Toyama
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YAKURA Takayuki
Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
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Yakura Takayuki
Graduate School Of Medicine And Pharmaceutical Sciences Univ. Of Toyama
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