P-100 SYNTHETHIC STUDY OF SPICULOIC ACID A

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P-100 SYNTHETHIC STUDY OF SPICULOIC ACID A
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Total syntheses of (+)-altholactone[(+)-goniothalenol] and three stereocongeners and their cytotoxicity against several tumor cell lines.
Synthesis of cytidine, uridine, and adenosine 5'-(2,6-diamino-2,6-dideoxy-.ALPHA.-D-glucopyranosyl diphosphates) (neosamine C-CDP, -UDP, and -ADP).
Claisen rearrangements of 5,6-dideoxy-1,2-o-isopropylidene-.ALPHA.-D-xylo- and .ALPHA.-D-ribo-hept-5-eno-1,4-furanoses with triethyl orthoacetate.
Syntheses of optically active pentaacetates of pseudo-.BETA.-L-allopyranose and pseudo-.ALPHA.-D-mannopyranose.
Construction of an optically active 7-oxabicyclo[4.3.0]non-4-en-3-one skeleton from D-glucose, and its transformation to some pseudo-hexopyranoses.
A synthesis of (+)-cyclaradine, carbocyclic analogue of 9-.BETA.-D-arabinofuranosyladenine.
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