Electrochemical Deposition of Regioregular Head-to-Tail Poly(3-hexylthiophene-2,5-diyl) and Characterization of the Obtained Film : Atoms, Molecules, and Chemical Physics
スポンサーリンク
概要
- 論文の詳細を見る
Films of p-doped regioregular head-to-tail-type poly(3-hexylthiophene), HT-P3HexTh, were formed on a Pt plate by electrochemical deposition of HT-P3HexTh in a tetrahydrofuran solution of [NBu_4]Y (Bu=butyl; Y=BF_4, PF_6, or ClO_4). The p-doped HT-P3HexTh molecules were oriented in the film with the hexyl group arranged essentially perpendicular to the surface of the Pt plate.
- 社団法人応用物理学会の論文
- 2001-03-01
著者
-
YAMAMOTO Takakazu
Chemical Resources Laboratory, Tokyo Institute of Technology
-
SASAKI Shintaro
Japan Advanced Institute of Science and Technology
-
Yamamoto Takakazu
Chemical Resources Lab. Tokyo Inst. Of Technol.
-
Kuroda Shin-ichi
Faculty Of Engineering Gunma University
-
KOKUBO Hisashi
Chemical Resources Laboratory, Tokyo Institute of Technology
-
KPLIBO Hisashi
Chemical Resources Laboratory, Tokyo Institute of Technology
-
Kplibo Hisashi
Chemical Resources Laboratory Tokyo Institute Of Technology
-
Kokubo Hisashi
Chemical Resources Lab. Tokyo Inst. Of Technol.
関連論文
- Novel Oligodipyridylamine Ligands with Chiral N-Alkyl Side Chains. Synthesis of Coordination Polymers Consisting of Copper Complexes Containing the Ligands and Their Crystal Structure and Optical and Magnetic Properties
- Highly Coplanar Polythiophenes with -C≡CR Side Chains : Self-Assembly, Linear and Nonlinear Optical Properties, and Piezochromism
- The Dynamic Structure of Regioregulated Poly(4-methylthiazole-2,5-diyl)
- Synthesis of 3,5-Dibromopyridines with -NH(CH_2)_mSO_3Na (m = 3 and 4) Groups at the 2-Position of Pyridine and Use of the Dibromo Compound for Polymer Synthesis
- Molecular Alignments Studied by X-Ray Diffraction Analysis and Optical Properties of Vacuum-Deposited Thin Films of Thiophene-Pyridine Co-Oligomers
- The First Observation of ^1H-NMR Spectrum of Pentacene
- Promotion of Reductive Elimination Reaction of Diorgano (2, 2' -bipyridyl) nickel (II) Complexes by Electron-Accepting Aromatic Compounds, Lewis Acids, and Bronsted Acids
- Preparation and Characterization of Regioregular Head-to-Tail π-Conjugated Poly(pyridine-2,5-diyl)s
- Synthesis and Chemical Properties of Poly(N-substituted diphenylamine-4,4'-diyl)s
- Synthesis of π-Conjugated Polymers by Organometallic Polycondensation
- Synthesis of Poly (3-nitropyridine-2,5-diyl) and Poly (3,3'-dinitro-2,2'-bipyridine-5,5'-diyl-) and Electrochemical Response
- Comparison of Packing Modes of Poly (thiophene)s and Poly (thiazole)s
- Intermolecular π-π Interraction of Poly (4, 4'-dialkyl -2, 2'-bithiazole - 5, 5'-diyl) s and Photoluminescence of the Polymers
- Direct Alkylation and Phenylation of 3, 8-Dibromo-1, 10-phenanthroline with Grignard Reagents
- Synthesis and Structural Features of a Series of κ^3SNS Pincer Complexes of Group 10 Metals σ-Bonded to Centered Pyrrolate Unit
- Stacking of Poly(3-alkylthiophene)s and Poly(4-alkythiazole)s in a Colloidal Solution and in the Solid
- Large Faraday Rotation in a π-Conjugated Poly(arylene ethynylene) Thin Film
- A New Class of Star-Shaped Discotic Liquid Crystal Containing a 2, 4, 6-Triphenyl-1, 3, 5-triazine Unit as a Core
- Electrochemical and Chemical Doping Behavior of Bithiophene-Bithiazole Copolymer
- Synthesis of Inclusion Compounds of Br-Th-Py-Br and (RO)_2B-Th-Py-Br (Th : Thiophene-2,5-diyl ; Py : Pyridine-2,5-diyl) with γ-Cyclodextrin
- X-Ray Analysis of Poly (thiophene-alt-thiophene-1,1-dioxide)
- Synthesis and Chemical Properties of π-Conjugated Poly (9,10-dialkyl-9,10-dihydrophenanthrene-2,7-diyl) and a Related Polymer
- Utilization of Industrially Available 2,3-Dichloro-1,3-butadiene for Direct Synthesis of 2,3-Diaryl-1,3-butadienes
- Synthesis, Structure, and Information about Molecular Weight of Thiophene Homopolymers, Copolymers of 2, 5-Thienylene and 2, 4-Thienylene, and Their Soluble Nitrates
- Preparation of Polyphenylenes with Higher Molecular Weights via Dehalogenative Polycondensation Using Magnesium and Aggregating Property of the Polymer in Solutions
- Preparation of New π-Conjugated Thiophene-Pyrrole Copolymers Having Ethynyl Substituents at the N-Position of Pyrrole
- Comparison of Optical Properties and Doping Behavior of -[(p-C_6H_4)_mNH]_n- (m = 1-4) Type Polymers
- Preparation of Chiral Poly(dipyridylamine). Its Metal Complex-controlled Steric Structure, and Its Light Emitting Properties
- π-Conjugated Poly(1,10-phenanthroline)-Ru^(bpy)_2 Complex as an n-Type Active Material for FET
- Preparation of Soluble π-Conjugated Poly(5, 6-dialkoxy-1, 10-phenanthroline-3, 8-diyl)s. Their Stacking Behavior and Function as a π-Conjugated Polymer Ligand
- Synthesis of New Thiophene-Based π-Conjugated Organic Compounds and Polymer
- Synthesis of 3-Alkynyl-2, 5-dibromothiophene and 3, 3'-Dialkynyl-5, 5'-dibromo-2, 2'-bithiophene as the Starting Compounds for π-Conjugated Polymer
- Acceleration Effect of a π-Conjugated Polymer-Modified Electrode for Electrolytic Evolution of H_2 in H_2SO_4(aq)
- Electrochemical Deposition of Regioregular Head-to-Tail Poly(3-hexylthiophene-2,5-diyl) and Characterization of the Obtained Film : Atoms, Molecules, and Chemical Physics
- Preparation of Soluble Polypyrrole with -C≡C-p-C_6H_4-hexyl Side Chains at the N-Position and Its Self-assembling Behavior
- Comparison of UV-Vis Changes Observed in Deprotonation of 2-Heptylbenzimidazole, 2-Heptyl-4, 7-diphenylbenzimidazole, and Poly(2-heptylbenzimidazole-4, 7-diyl)
- Preparation of Poly(9,10-dihydrophenanthrene-2,7-diyl) Consisting of a Chiral C_2-Symmetrical Monomeric Unit and Optical Properties of the Polymer
- p-Doping of Poly(3-hexylthiophene-2, 5-diyl) with Sulfonic Acids and Oxygen Related to Self-doping of Sulfonated Polythiophenes
- Synthesis and Electrochemical Properties of New Main Chain Type Polyquinones Constituted of Thiophene-Fused Benzoquinone and Transformation of the Polymers to a Dicyanoquinonediimine Type Polymer
- Inclusion of Polyaniline in the Channel Constructed from Tris(2,3-naphthylenedioxy)cyclotriphosphazene
- Self-Assembly and Oriented Structures on Surface of Substrates for $\pi$-Conjugated and Coplanar Polythiophenes with –C$\equiv$CR Substituents
- Self-assembly of Donor and Acceptor π-Conjugated Molecules via Complexation with γ-Cyclodextrin to Give a Pseudorotaxane Type Macromolecular Adduct with an Expanded π-Conjugation System
- Preparation of Head-to-tail π-Conjugated Poly(thiophene-pyridine) and Polypyrimidine by Organometallic Polycondensation
- Study on Relationship between Electroluminescence Properties and Molecular Weight Distribution of Poly(9,9$'$-dioctylfluorene) Using Photoluminescence
- π-Conjugated Polymers, (Th(R)-CH=CH-Th(R))_n (Th(R)=3-Alkylthiophene-2,5-diyl ; R = Octyl, Decyl, and Dodecyl) : Preparation of Dibromo Monomers and the Polymers
- Molecular Alignments Studied by X-Ray Diffraction Analysis and Optical Properties of Vacuum-Deposited Thin Films of Thiophene–Pyridine Co-Oligomers
- The First Observation of 1H-NMR Spectrum of Pentacene
- Optical Properties and Microcapillary Laser of Blue-Emissive $\pi$-Conjugated Polymers Based on 9,10-Dihydrophenanthrene Unit
- Time-Resolved Photoluminescence Study and Microcapillary Laser of Blue-Emissive $\pi$-Conjugated Polymers Based on 9,10-Dihydrophenanthrene Unit
- Purification of Head-to-Tail-Type Regioregular Poly(3-hexylthiophene), HT-P3HexTh, and Investigation of the Effects of Polymer Purity on the Performance of Organic Field-Effect Transistors
- Large Faraday Rotation in a $\pi$-Conjugated Poly(arylene ethynylene) Thin Film
- Preparation of Ferromagnetic $m$-Phenylene-Type Copolymer Containing Thiophene Derivatives in the Side Chain
- Study on Relationship between Electroluminescence Properties and Molecular Weight Distribution of Poly(9,9$'$-dioctylfluorene) Using Photoluminescence