Synthesis of 2-Methoxy-4H-1,3,2-benzodioxaphosphorin 2-Sulfide and Related Compounds Utilizing Intramolecular Cyclization Reactions(Organic Chemistry)

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概要

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• The insecticide salithion (2-methoxy-4H-1,3,2-benzodioxaphosphorin 2-sulfide) and its 4-cyano derivatives were prepared in good yields by utilizing an intramolecular cyclization reaction as the key step. The structures of diastereomers of the 4-cyano derivatives were characterized on the bases of NMR spectroscopy and X-ray analysis.

• 社団法人日本農芸化学会の論文
• 1988-01-23

著者

• Moriguchi Koichi

  Takatsuki Research Laboratory Sumitomo Chemical Co. Ltd.

• Sasaki M

  Tokyo Univ. Tokyo Jpn

• SASAKI Mitsuru

  Pesticides Research Laboratory, Takarazuka Research Center, Sumitomo Chemical Co., Ltd.

• YANAGI Kazunori

  Takatsuki Research Laboratory, Sumitomo Chemical Co., Ltd.

• Yanagi K

  Takatsuki Research Laboratory Sumitomo Chemical Co. Ltd.

• Yanagi Kazunori

  Takatsuki Research Laboratory Sumitomo Chemical Co. Ltd.

• Sasaki Mitsuru

  Pesticides Research Laboratory Takarazuka Research Center Sumitomo Chemical Co. Ltd.

関連論文

• Synthesis of 2-Methoxy-4H-1,3,2-benzodioxaphosphorin 2-Sulfide and Related Compounds Utilizing Intramolecular Cyclization Reactions(Organic Chemistry)
• Isolation of Aristolochic Acid and Aristolic Acid from Cocculus triolobus DC as Potent Seed Germination Inhibitors(Organic Chemistry)
• 1H-1, 2, 4-Triazol- 1-ylmethyldiphenyl-phosphine Sulfides, a New Class of Fungicides
• Synthesis of Highly Pure Enantiomers of the Insecticide Salithion

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