Methyl 9-(2-(2,5-Dihydro-5-pentylfuryl))-nonanoate in the Copper-catalyzed Decomposition Products of Methyl Linoleate Hydroperoxides and Some Other Products(Food & Nutrition)

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概要

• 論文の詳細を見る

• The hydroperoxide of methyl linoleate containing 95% 13-hydroperoxide and 5% 9-hydroperoxide was decomposed in benzene with 10^<-4>M cupric naphthenate at 75〜80℃ under degassed conditions. The decomposition products were fractionated by Sephadex LH-20 column chromatography with chloroform-hexane (2:1, v/v) and the fractions were purified by HPLC. In addition to the known products, three compounds were identified as methyl 9-(2-(2,5-dihydro-5-pentylfuryl))-nonanoate, methyl 8-(2-furyl)-octanoate, and methyl 9(13)-hydroperoxy-12,13-(9,10)-epoxy-10(12)-octadecenoate as miner decomposition products by MS and IR spectro-photometry.

• 社団法人日本農芸化学会の論文
• 1987-02-23

著者

• Morita M

  Meijo Univ. Nagoya Jpn

• Morita Makio

  Department Of Food And Nutrition Japan Women's University

• Tokita Masako

  Department Of Food And Nutrition Japan Women's University

関連論文

• Autocatalytic Activity in the Low-Polarity Part of Autoxidizing Methl Linolenate(ノ-ト)
• New Geometric Isomers of Oxooctadecadienoate in Copper-catalyzed Decomposition Products of Linoleate Hydroperoxide
• Identification of New Geometric Isomers of Methyl Linoleate Hydroperoxide and Their Chromatographic Behavior
• Methyl 9-(2-(2,5-Dihydro-5-pentylfuryl))-nonanoate in the Copper-catalyzed Decomposition Products of Methyl Linoleate Hydroperoxides and Some Other Products(Food & Nutrition)
• Influence of Linoleate Hydroperoxide Minor Isomers on GLC Analysis of Oleate Hydroperoxides
• Different Rates of Geometric Isomers of Linoleate Hydroperoxide in Acid-catalyzed Decomposition
• Methyl Linoleate Dimer and Methyl 8-Phenyloctanoate in the Coppercatalyzed Decomposition Products of Methyl Linoleate Hydroperoxides

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