Identification of New Geometric Isomers of Methyl Linoleate Hydroperoxide and Their Chromatographic Behavior

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概要

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• New geometric isomers, methyl (9Z, 11Z)-13-hydroperoxy-9,11-octadecadienoate and methyl (10Z, 12Z)-9-hydroperoxy-10,12-octadecadienoate, were proved to be present in methyl linoleate hydroperoxide produced by antoxidation. They were identified from their UV, MS, and ^1H-NMR spectra after conversion to the corresponding oxo derivatives : methyl (9Z, 11Z)-13-oxo-9,11-octadecadienoate and methyl (10Z, 12Z)-9-oxo-10,12-octadecadienoate. Their chromatographic behavior is described.

• 社団法人日本農芸化学会の論文
• 2000-05-23

著者

• Morita Makio

  Department Of Food And Nutrition Japan Women's University

• Tokita Masako

  Department Of Food And Nutrition Japan Women's University

関連論文

• Autocatalytic Activity in the Low-Polarity Part of Autoxidizing Methl Linolenate(ノ-ト)
• New Geometric Isomers of Oxooctadecadienoate in Copper-catalyzed Decomposition Products of Linoleate Hydroperoxide
• Identification of New Geometric Isomers of Methyl Linoleate Hydroperoxide and Their Chromatographic Behavior
• Methyl 9-(2-(2,5-Dihydro-5-pentylfuryl))-nonanoate in the Copper-catalyzed Decomposition Products of Methyl Linoleate Hydroperoxides and Some Other Products(Food & Nutrition)
• Influence of Linoleate Hydroperoxide Minor Isomers on GLC Analysis of Oleate Hydroperoxides
• Different Rates of Geometric Isomers of Linoleate Hydroperoxide in Acid-catalyzed Decomposition
• Methyl Linoleate Dimer and Methyl 8-Phenyloctanoate in the Coppercatalyzed Decomposition Products of Methyl Linoleate Hydroperoxides

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