Rearrangement. VIII. Pyrolysis of cis-and trans-2-Methylcyclohexyl p-Toluenesulfonates
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概要
- 論文の詳細を見る
The pyrolysis of cis- and trans-2-methylcyclohexyl p-toluenesulfonates in the liquid phase at 180°gave methylcyclohexane (21 and 18%), 1-methylcyclohexene (55 and 55%), 3-methylcyclohexene (22 and 25%), and methylenecyclohexane (2 and 2%). The results obtained, together with those reported previously, support the conclusion that the pyrolysis may proceed, at least in part, through a free radical process. Nonstereospecificity in the direction of the pyrolysis may rule out a radical pair mechanism involving hydrogen participation.
- 大阪府立大学の論文
- 1968-03-31
著者
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TATSUMI Chuji
Department of Agricultural Chemistry, College of Agriculture
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Kotani Ryotaro
Department Of Agricultural Chemistry
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Tatsumi Chuji
Department Of Agricultural Chemistry
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