Conversion of Acetone to Aromatic Chemicals with HZSM-5
スポンサーリンク
概要
- 論文の詳細を見る
Monoaromatic compounds are important chemicals as raw material for many petrochemical industries. Conventionally, these compounds are obtained from fossil resources by petroleum refining processes. In order to reduce the dependency on this resource, a new route with the utilization of biomass as starting material for the production aromatic chemicals is considered to establish a sustainable system of chemical industry. The route is that acetone could be produced selectively by catalytic reaction from biomass-derived oil. From this point, therefore, this study is to explore a catalytic conversion of acetone toward aromatic chemicals with HZSM-5. The reaction is carried out by continuous flow reactor at an atmospheric pressure to examine the activity and selectivity of HZSM-5. Some parameters such as temperature, space velocity, effect of water have been investigated. The results show that HZSM-5 exhibited a high active and a shape-selective catalyst for the formation of monoaromatic chemicals. The favourable condition for acetone aromatization is found i.e. at 673 K with space velocity of 4 h^<-1>, the acetone conversion is close to 100 % and monoaromatic selectivity is approximately 71 %. The low selectivity of carbon oxides (less than 5 %) was obtained, and it could be contributed significantly for this catalytic reaction on realization toward sustainable development of chemical industry in the future. There is no effect of water existence in the acetone feed on the aromatization reaction process, making the process will be simplified.
- 一般社団法人日本エネルギー学会の論文
- 2003-12-20
著者
-
Setiadi Suprapto
Department Of Applied Chemistry Faculty Of Engineering Seikei University
-
Tsutsui Toshio
Department Of Applied Chemistry And Chemical Engineering Faculty Of Engineering Kagoshima University
-
Kojima Toshinori
Department Of Information And Computer Science Keio University
-
Kojima Toshinori
Department Of Applied Chemistry Faculty Of Engineering Seikei University
関連論文
- E. camaldulensis Optimal Planting Density in Desert Western Australia in View of Its Photosynthetic Properties
- Management of Salinity and Afforestation by IRS 1D LISS-III Data in North Bihar, India
- Tetrameric short tandem repeat (STR) system D15S233 (wg1d1) : Sequencing and frequency data in the Japanese and Chinese populations
- Crystallization behavior of new transparent glass-ceramics based on barium borate glasses
- Improvement of Fluidized State of Geldart's A-Type Particles with Smooth Surface by Ultra-Fine Powder Addition
- Improvement Effect of Semi-Arid Land Afforestation on Soil Environment
- Relation between Growth of Planted Trees and Soil Chemical Properties in Afforestation Sites of Semi-arid Land, WA
- Basic data of research project on large scale afforestation of arid land for carbon fixation near Leonora in Western Australia (小特集 沙漠工学分科会)
- Development of Tree Growth Simulator Based on a Process Model of Photosynthesis for Eucalyptus Camaldulensis in Arid Land
- A Modeling Methodology of Large Scale Water Balance and Salt Accumulation for Afforestation in Arid Land
- Death of Trees in the Wheat Belt in Western Australia : Identification of the Causes by Chemical Analysis of Soil
- Development of Integrated Simulator of Water Transport and Plant Growth as an Evaluation Tool of Arid Land Afforestation for CO_2 Fixation
- Comparative Analysis between Biomass and Topographic Features in an Arid Land, Western Australia
- Restructuring and Afforestation of Hardpan Area to Sequester Carbon
- Photocatalytic Activity of Magnetically Separable TiO2/SiO2/Fe3O4 Composite for Dye Degradation
- Establishment and Evaluation of the Method for Estimation of Water Use Efficiency of a Tree
- Mono-core Coating of Fine Particles with Finer Particles by Means of a Draft-Tube Spouted-Bed with Medium Particles
- A Strategy for Efficient Update Propagation on Peer-to-Peer Based Content Distribution Networks
- Fluidization and Surface-to-Bed Heat Transfer Coefficient in Fluidized Beds of Very Fine Ni and Ni-Alloy Powders
- Fabrication of Thin Palladium-Silver Alloy Film by Using Electroplating Technique
- Practical Approach to Integrating Network Coordinates with Distributed Hash Tables
- Factors Affecting Distribution of Nutrient in Tree Organs of Eucalyptus camaldulensis in Arid Lands of Western Australia
- TED-AJ03-143 A UNIQUE MEASUREMENT METHOD FOR GASIFICATION REACTIVITY OF SINGLE CHAR PARTICLES UNDER CONDITION OF ENTRAINED FLOW GASIFIERS
- Conversion of Acetone to Aromatic Chemicals with HZSM-5
- A Numerical Study on a Single Char Particle Combustion Around Ash Melting Temperature
- Gasification of Seven Coals in Carbon Dioxide at Elevated Temperatures and High Heating Rates: Unification Approach of Reactivity
- P2P-Based Approach to Finding Replica Server Locations for Alleviating Flash Crowds
- Water Use Efficiency of Eucalyptus camaldulensis Growing in Arid Regions in Western Australia
- Quantitation of DNA from Flow Cytometry Analysis Using Fluorescent Probe
- Hydration Behaviour of Ecocement in Presence of Metakaolin (日韓資源リサイクル・材料化学に関する国際シンポジウム特集号)
- Effect of Carboxy Methyl Cellulose Gel on Thermal Energy storage of Ground Shallow Solar Pond
- Effect of Climate and Soil Condition on Oil Content of Jatropha Plants Grown in Arid Areas of India
- GIS-Based Estimation of Global Carbon Sequestration Potential Due to Forest Management
- Design and Development of Solar IT Kiosk for Remote Area Development in Arid Regions of Bihar, India
- Estimation of Carbon Sequestration Potential of Arid Land Afforestation Using Satellite Image Analysis and Ground Truth
- Selection of Afforestation Methods for Eucalyptus sargentii as a Countermeasure to Climate Change and Salinity Problem : A Case Study of Wheat Belt Area in Western Australia
- Allometric Equations and Biomass Amount of Representative Tunisian Arid Land Shrubs for Estimating Baseline
- Appropriate Technology Requirement and Impact Projection for Rural Women in Arid Region of India
- Effect of Difference in Rainfall Patterns and Intensities on Runoff Simulation Results in Arid Land
- Sulphur dioxide retention by calcined limestone under oxygen lean conditions.
- Reaction by the enzyme entrapped by UF membrane with acceleration of mass transfer by pressure swing.
- Factors Affecting the Distribution of Nutrients in the Tree Organs of Eucalyptus camaldulensis in the Arid Lands of Western Australia
- Establishment and Evaluation of a Method for the Estimation of the Water Use Efficiency of a Tree
- Kinetic study of monosilane pyrolysis for polycrystalline silicon production in a fluidized bed.
- Properties of silicon produced by monosilane pyrolysis.
- Measurement of solids behaviour in a fast fluidized bed.
- Photocatalytic Activity of Magnetically Separable TiO_2/SiO_2/Fe_3O_4 Composite for Dye Degradation
- GIS-Based Estimation of Global Carbon Sequestration Potential Due to Forest Management
- Effect of Carboxymethyl Cellulose Gel on Thermal-Energy Storage by Ground Shallow Solar Ponds
- Determination of Gas Flow Pattern in a Test Coke Oven Charge and Its Time Variation by Tracer Technique.
- Effects of Water Supply on the Growth Rate and Water Use Efficiency of Trees in Arid Land Afforestation in Western Australia
- Effects of Increase in Gas Volume on the Fluidization Properties in Fluidized Bed Reactors
- Decomposition of Harmful Organic Compounds with Ultrasound Wave
- The Influence of Soil and Organic Matter on Trichloroethylene Decomposition by Fenton Reaction