Thermodynamic Stability and Melting of Crystals in a Bulk Polymer

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概要

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• A lattice theory is developed for a partially crystalline polymer on the assumption that an equilibrium between crystalline and noncrystalline regions is attained under a limited condition. The two extreme cases, where the noncrystalline part is exclusively composed of either chain loops or tie chains connecting different crystals, are treated by considering both intra- and interchain interactions along with the amorphous chain length distribution. The rise in the melting point of a bulk crystalline polymer on stretching is well explained by applying an appropriate criterion to it.

• 社団法人応用物理学会の論文
• 1975-01-05

著者

• Ishinabe Takao

  Faculty Of Engineering Tokyo Institute Of Technology:faculty Of Engineering Yamagata University

• Ishinabe Takao

  Faculty Of Engineering Tokyo Institute Of Technology

関連論文

• Thermodynamic Stability and Melting of Crystals in a Bulk Polymer
• Application of the Coherent Anomaly Method to 1/d Expansions for a Self-Interacting Self-Avoiding Lattice Walk(New Developments in Statistical Physics Similarities in Diversities,YITP Workshop)
• A Molecular Theory of the Thermal Transitions of Polymers. I.
• CRITICAL EXPONENTS OF SAW AT THE θ POINT IN TWO DIMENSIONS(Session I : Cross-Disciplinary Physics, The 1st Tohwa University International Meeting on Statistical Physics Theories, Experiments and Computer Simulations)
• Phase Transition in Crystals of Semiflexible Long-Chain Molecules. : I
• Phase Transition in Crystals of Semiflexible Long-Chain Molecules.II
• A Molecular Theory of the Thermal Transitions of Polymers. II.
• Theory of the Rotational Phase Transition in Normal Paraffine Crystals

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