Photovoltaic Effect of Bilayer Solid-State Cell with Polysiloxane Pendant Tris (2,2'-bipyridyl) ruthenium Complex
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概要
- 論文の詳細を見る
A solid-state photoelectrochemical device was fabricated with a poly-siloxane pendant tris(2,2'-bipyridyl) ruthenium complex [PSiO-Ru(bpy)^<2+>_3] as a photosensitizer layer and a polysiloxane pendant methylviologen [PSiO-MV^<2+>] as an electron acceptor layer. In the dark, the SnO_2/PSiO-MV^<2+>/PSiO-Ru(bpy)^<2+>_3/Ag solid-state cell showed rectification characteristics. Photocurrent was obtained in the bilayer solid-state cell upon illumination of visible light, which was caused by the photoexcitation of the Ru(bpy)^<2+>_3 and successive electron transfer to the MV^<2+>. The short-circuit photocurrent of 0.485 μA・cm^<-2> ' was obtained with the intensity of illumination of 34mW・cm^<-2>
- 社団法人応用物理学会の論文
- 1994-04-01
著者
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Ikeda Koji
Department Of Cardiology Kyoto Prefectural University Of Medicine
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Kaneko Masao
Department Of Chemistry Ibaraki University
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Yamada Katsumi
Graduate School Of Science And Technology Chiba University
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KOBAYASHI Norihisa
Department of Image Science, Chiba University
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HIROHASHI Ryo
Department of Image Science, Chiba University
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Hirohashi R
Chiba Univ. Chiba Jpn
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Ikeda Koji
Department Of Image Science Chiba University
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Ikeda Koji
Department Of Anesthesiology Kagoshima City Hospital
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Kobayashi Norihisa
Department Of Image Science Chiba University
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Hirohashi Ryo
Department of Image Science and Engineering, Faculty of Engineering, Chiba University
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