Electrochromic Properties of Nickel Oxide Films Prepared by the Oxidation of Nickel-Carbon Composite Films
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概要
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Electrochromic (EC) nickel oxide (NiO) films were prepared either by plasma oxidation of vacuum-deposited nickel-carbon (Ni-C) composite films or by thermal oxidation of those films. EC properties of the NiO films were measured by cyclic voltammetry in 1 M KOH. The degree of electrochromism in the NiO films depended not only on the Ni-to-C (Ni/C) ratio in the Ni-C films but also on the oxidation conditions of the Ni-C films. The NiO film with a Ni/C ratio of ∼ 0.6 showed the longest cycling ability among the films with three different Ni/C ratios (∼0.3, ∼0.6 and ∼1.2). The NiO film thermally oxidized at 500℃ showed smaller transmission modulation and passed charge density than the plasma oxidized film, but could be electrochemically switched for more than 5000 cycles without serious residual coloration.
- 社団法人応用物理学会の論文
- 1996-12-15
著者
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MURAI Kensuke
Osaka National Research Institute
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Murai Kensuke
Osaka National Research Institute Aist
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TAMURA Shigeharu
Osaka National Research Institute
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SATO Yoshiyuki
Osaka National Research Institute, AIST
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Tamura Shigeharu
Osaka National Research Institute Aist
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Sato Yoshiyuki
Osaka National Research Institute Aist
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