Molecular Orientation and Growth Direction of Polydiacetylene Single-Crystal Monolayer at Air-Water Interface
スポンサーリンク
概要
- 論文の詳細を見る
A large single crystal of polydiacetylene monolayer (20×7 mm) was fabricated and the surface structure at the air-water interface analyzed. The surface expansion and unidirectional supply of the film material promoted alignment along the growth direction and crystalline order. Interfacial in-situ microscopy revealed the surface structure of the monolayer to be associated with the facilitated monomer growth and the solid-state polymerization. A novel detection system enabled the observation of polarized fluorescence from the conjugated chain of the polydiacetylene monolayer at the interface. Long-range ordering in the conjugated polymer chains persists along one direction throughout a domain.
- 社団法人応用物理学会の論文
- 1996-08-15
著者
-
Yamada Susumu
Department Of Electrical Engineering Tomakomai National College Of Technology
-
Shimoyama Yuhei
Department Of Physics Faculty Of Education Hokkaido University Of Education
-
Shimoyama Yuhei
Department of Materials Science and Engineering, Muroran Institute of Technology, Muroran, Hokkaido 050-8585, Japan
関連論文
- Self-Assembly Process of Alkanethiol Monolayers
- Phase Transitions and Structures in Langmuir-Blodgett Films
- Growth of Self-Assembled Monolayer of Thiophene on Gold Surface : An Infrared Spectroscopic Study : Surfaces, Interfaces, and Films
- Enhanced Orientation in Langmuir-Blodgett Films of Tetra-tert-butyl Phthalocyanines
- Preparatiorn of Oriented Large Domains of Diacetylene Monolayer at the Air-Water Interface
- Investigation of Slow Dynamics of the Sulfhydryl in the Solution and Gel States of Bovine Serum Albumin : A Vector Electron Paramagnetic Resonance Study
- Molecular Orientations in Langmuir-Blodgett and Vacuum-Deposited Films of VO-Phthalocyanine
- Fabrication and Structure of Langmuir–Blodgett Films of Nitrostilbene
- Structures of Self-Assembled Monolayers versus Vacuum Deposited Films of Terthiophene
- Fabrication of Langmuir-Blodgett Films of β-carotene by Flow-orientation
- Molecular Orientation and Growth Direction of Polydiacetylene Single-Crystal Monolayer at Air-Water Interface
- X-Ray Diffraction study of Langmuir-Blodgett Films of Mn-Arachidate
- A Frequency Modulation Detection Scheme of Electron Paramagnetic Resonance Spectroscopy
- Morphological Variation of the Monolayer Surface of Diacetylene during Polymerization at Air-Water Interface
- Experimental Evidence for Nanostructural Tube Formation of Silicon Atoms
- Molecular Orientation and Electromagnetic Properties of Perhydrogenated and Perfluorinated Copper Phthalocyanine Thin Films