Effects of Uniaxial Compaction Pressure on the Dielectric Properties of BaTiO_3 /Polyvinylidene Fluoride Composites

概要

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In this study, the formation of internal stress, domain switching, phase transition, and dielectric property variations of BaTiO_3 particles in the BaTiO_3-PVDF composites are investigated. It is found that the characteristics of the composite are highly affected by the magnitude of the compaction pressure employed. The internal stress may change from a state of compressive to tensile as the pressure increases. This is characterized by domain switching, in which the c axis rotates 90°, leaning from perpendicular to tire sample surface to parallel. Mean while, a larger compaction pressure favors the formation of orthorhombic (o-) BaTiO_3, which can result from the effects of internal stress and crystallite size. Composites made of BaTiO_3 crystallites with higher internal stress and o-BaTiO_3 contents may have higher values of the dielectric constant.
社団法人応用物理学会の論文
1994-07-15