UV Absorption Study on the Reaction of Methyl Radicals behind Shock Waves
スポンサーリンク
概要
- 論文の詳細を見る
By using the shok tube technique, the effective decadic molar extinction coefficient (ε) of methyl radicals was determined at temperatures between 1400 and 2400 K in the range of the ^2A'_1-~2A"_2 electronic transition between 2100 and 2250Å. This ε had the maximum value at 2160Å and decreased with an increase in increase in temperature. The rate constant for the reaction CH_3 + CH_3 except the recombination to ethane was K_5=9.7 X 10^15 exp(-128 KJ/mol/RT)cm^3/MOL s at temperatures between 1600 and 2000 K. The rate constants for the decomposition of ethane were dependent on the density in the range between 2 x 10^-6 and 1.5 x 10^-4mol/cm^3.
- 社団法人応用物理学会の論文
- 1978-04-05
著者
関連論文
- Further Study on Temperature, Density, and Perturber Dependences of Absorption of 3.39 μm He-Ne Laser by Methane
- High-Temperature Absorption by Pure CO_2 Far Line Wings in the 4 μm Region
- Temperature, Density, and Perturber Dependences of Absorption of the 3.39 μm He-Ne Laser by Methane
- Temperature Measurement of a Propagating Flame Using UV-Absorption of CO_2
- On Induction Periods of Shock-Heated Methane-Oxygen-Argon-Mixtures
- Thermal Decomposition of Methanol behind Shock Waves
- Deformation of Needle in the High Temperature Gas behind Detonation Wave
- Mechanism of Momogeneous Thermal Oxidation of Ethane
- Light Absorption by Hydrocarbon Molecules at 3.392 μm of He-Ne Laser
- UV Absorption Study on the Reaction of Methyl Radicals behind Shock Waves
- Mechanism for the Homogeneous Thermal Oxidation of Methane in the Gasphase