Thermal Decomposition of Methanol behind Shock Waves

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概要

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• The thermal decomposition of methanol in argon behind incident and reflected shock waves is studied. The reaction was followed by ultraviolet (UV) absorption between 1900 and 2200 Å and by infrared (IR) emission of methanol at wavelengths 2.4-2.9 μm, 3.1-3.9 μm and 4.8-5.2 μm and of formed species at wavelengths 2.7 μm, 3.6 μm and 4.9 μm. The temperature and the density dependences of the decomposition rate constants were observed at temperatures from l500 to 1900 K, at total densities from 10^<-5> to 2×10^<-4> mol/cm^3 and at concentrations from 0.01 % to 1.0 % methanol. The experimentally-determined signals are compared with the calculated values and the density-dependent rate constants of the unimolecular reaction of methanol are obtained.

• 社団法人応用物理学会の論文
• 1981-05-05

著者

• Katoh Masataka

  Faculty Of Engineering Yokohama National University

• TSUBOI Takao

  Faculty of Engineering, Yokohama National University

• Tsuboi Takao

  Faculty Of Engineering Yokohama National University

• Kikuchi Shigeru

  Faculty Of Engineering Yokohama National University

• HASHIMOTO Kazunobu

  Faculty of Engineering, Yokohama National University

• Hashimoto Kazunobu

  Faculty Of Engineering Yokohama National University

関連論文

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• Temperature, Density, and Perturber Dependences of Absorption of the 3.39 μm He-Ne Laser by Methane
• Temperature Measurement of a Propagating Flame Using UV-Absorption of CO_2
• On Induction Periods of Shock-Heated Methane-Oxygen-Argon-Mixtures
• ESR Centers in Fused Quartz Exposed to Glow-Discharge Plasmas of Ar and H_2 : Condensed Matter
• Thermal Decomposition of Methanol behind Shock Waves
• Deformation of Needle in the High Temperature Gas behind Detonation Wave
• Mechanism of Momogeneous Thermal Oxidation of Ethane
• Light Absorption by Hydrocarbon Molecules at 3.392 μm of He-Ne Laser
• UV Absorption Study on the Reaction of Methyl Radicals behind Shock Waves
• Mechanism for the Homogeneous Thermal Oxidation of Methane in the Gasphase

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