Mechanism for the Homogeneous Thermal Oxidation of Methane in the Gasphase
スポンサーリンク
概要
- 論文の詳細を見る
To obtain the mechanism for the oxidation of methane-oxygen-argon mixtures product profiles were calculated by the numerical integration of 39 reactions and compared with the experimental results. The induction periods determined by the calculation were then compared with the induction periods obtained from experiments. The calculated results agree with the experimental results within the experimental error. From this comparison one obtains k_7=6×10^<13>, k_8=9×10^<11> exp (-50 kJ/mol/RT), k_<14>=1.0×10^<14> exp (-92 kJ/mol/RT) cm^3/mol sec in the temperature range between 1500 and 2000 K as the suitable rate constants for the reactions CH_3+O→CH_2O+H (7), CH_3+O_2→CH_2O+OH (8), CHO+Ar→CO+H+Ar (14) respectively. From this comparison a reaction scheme for the methane oxidation is obtained.
- 社団法人応用物理学会の論文
- 1976-01-05
著者
関連論文
- Further Study on Temperature, Density, and Perturber Dependences of Absorption of 3.39 μm He-Ne Laser by Methane
- High-Temperature Absorption by Pure CO_2 Far Line Wings in the 4 μm Region
- Temperature, Density, and Perturber Dependences of Absorption of the 3.39 μm He-Ne Laser by Methane
- Temperature Measurement of a Propagating Flame Using UV-Absorption of CO_2
- On Induction Periods of Shock-Heated Methane-Oxygen-Argon-Mixtures
- Thermal Decomposition of Methanol behind Shock Waves
- Deformation of Needle in the High Temperature Gas behind Detonation Wave
- Mechanism of Momogeneous Thermal Oxidation of Ethane
- Light Absorption by Hydrocarbon Molecules at 3.392 μm of He-Ne Laser
- UV Absorption Study on the Reaction of Methyl Radicals behind Shock Waves
- Mechanism for the Homogeneous Thermal Oxidation of Methane in the Gasphase