INTERCALATION OF A CROWN-ETHER INTO LAYERED SILICATES

スポンサーリンク

概要

• 論文の詳細を見る

• Intercalation of a crown ether (1 8-crown-6) into layered silicates was investigated. Intercalation compounds with the basal spacings of Ca. 1.9 nm were obtained by the solid-state reactions between K-, Rb-, and NH_4-montmorillonites and 18-crown-6, while the basal spacings of the products were different (1.4, 1.5, and 1.5 nm for K-, Rb-, and NH_4-montmorillonites, respectively) when a methanolic solution of 18-crown-6 was employed. 18-crown-6 was intercalated into the interlayer space of non swelling K-fluor-tetrasilicic mica probably due to the strong interactions between interlayer cations and 18-crown-6. The reaction between K-kenyaite and 18-crown-6 gave an intercalation compound with the basal spacing of Ca. 3.0 nm. It has been proved that the reactions between the layered silicates and 18-crown-6 without solvents are novel synthetic ways to lead intercalation compounds.

• 日本粘土学会の論文

著者

• KATO CHUZO

  Department of Applied Chemistry, Waseda University

• OGAWA Makoto

  PRESTO, Japan Science and Technology Corporation (JST)

• KURODA Kazuyuki

  Kagami Memorial Laboratory for Materials Science and Technology, Waseda University

• Kuroda Kazuyuki

  Kagami Memorial Laboratory For Materials Science And Technology Waseda University

• Ogawa Makoto

  Presto Japan Science And Technology Corporation

• KADOMOTO HIDEKI

  Institute of Earth Science, Waseda University

• Kadomoto Hideki

  Institute Of Earth Science Waseda University

• Ogawa M

  Division Of Clinical Chemotherapy Cancer Chemotherapy Center Japanese Foundation For Cancer Research

• Kato C

  Department Of Applied Chemistry Waseda University

• Kato Chuzo

  Department Of Applied Chemistry School Of Science And Engineering Waseda University

• Ogawa M

  Waseda Univ. Tokyo Jpn

• Kuroda K

  Department Of Applied Chemistry School Of Science And Engineering Waseda University:kagami Memorial

関連論文

• PREPARATION OF NICKEL ALUMINUM DOUBLE HYDROXIDES FROM HEXAAMMINENICKEL (II) COMPLEX SOLUTION
• Adsorption of Phenols onto 1, 1'-Dimethyl-4, 4'-bipyridinium-smectites
• Synthesis of a Soluble Precursor Possessing an Nb-N Backbone Structure and Its Pyrolytic Conversion into Niobium-Based Ceramics
• INTERCALATION OF A CROWN-ETHER INTO LAYERED SILICATES
• INTERCALATION AND THE PHOTOCHROMISM OF AZO DYE IN THE HYDROPHOBIC INTERLAYER SPACES OF ORGANOAMMONIUM-FLUOR-TETRASILICIC MICAS
• Selective Solid-State Intercalation of cis-trans Isomers into Montmorillonite
• PREPARATION OF MONTMORILLONITE-ALKYLAMINE INTERCALATION COMPOUNDS BY SOLID-SOLID REACTIONS
• PREPARATION OF MONTMORILLONITE-POLYACRYLAMIDE INTERCALATION COMPOUNDS AND THE WATER ABSORBING PROPERTY
• INCORPORATION OF THIOACETAMIDE INTO THE INTERLAYER SPACE OF MONTMORILLONITE BY SOLID-SOLID REACTIONS
• PREPARATION OF A KAOLINITE-ACRYLIC ACID INTERCALATION COMPOUND AND THE HEAT-TREATED PRODUCTS
• Preparation of Copper-Aluminum Double Hydroxides by a Coprecipitation Method
• THE CARBOTHERMAL REDUCTION PROCESS OF 2 : 1 TYPE CLAY MINERALS
• SYNTHESIS OF HEPTYLVIOLOGEN-MONTMORILLONITE-POLYMER INTERCALATION COMPOUNDS AND THEIR ELECTROCHEMICAL BEHAVIOR
• PREPARATION OF COBALT ALUMINUM DOUBLE HYDROXIDES BY A COPRECIPITATION METHOD
• A COMPARISON OF A NEW NITROSOUREA DERIVATIVE, 1-(2-CHLOROETHYL)-3-ISOBUTYL-3-(β-MALTOSYL)-1-NITROSOUREA WITH VARIOUS ANTITUMOR AGENTS WITH RESPECT TO THERAPEUTIC RATIOS IN L1210 LEUKEMIA SYSTEMS
• INTERCALATION OF AN AMPHIPHILIC AZOBENZENE DERIVATIVE INTO THE INTERLAYER SPACE OF CLAYS
• Novel Layered Silica/Organic Polymer Hybrid Films with the Interface Linked by Si-C Bonds
• Preparation of Inorganic-Organic Nanocomposites through Intercalation of Organoammonium Ions into Layered Silicates
• THE SYNTHESIS OF DIHEXADECYLVIOLOGEN-MONTMORILLONITE-TETRAPHENYLPORPHINE INTERCALATION COMPOUNDS AND THE PHOTOCHEMICAL REACTIONS
• Synthesis of kaolinite-lactam intercalation compounds.
• Organic derivatives of layered polysilicates. II. Reaction of magadiite and kenyaite with diphenylmethylchlorosilane.
• Synthesis of layered polysilicic acid-acrylamide intercalation compounds and polymerization in the interlayer spaces.
• The effect of tetraalkylammonium ions on the distribution of the silicate anions in aqueous solutions.
• Formation of hydrotalcite-acrylate intercalation compounds and their heat-treated products.
• The preparation of alkyltrimethylammonium-kanemite complexes and their conversion to microporous materials.

もっと見る 閉じる

スポンサーリンク