INTERCALATION OF AN AMPHIPHILIC AZOBENZENE DERIVATIVE INTO THE INTERLAYER SPACE OF CLAYS

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概要

• 論文の詳細を見る

• The intercalation of an amphiphilic cationic azobenzene derivative into the interlayer space of clays has been conducted by the ion exchange reactions between clays and p-(ω-trimethylammoniopentyloxy)-p'-(dodecyloxy)azobenzene bromide. The X-ray diffraction and the element alanalysis results indicated that the dye cations were intercalated into the interlayer space of clays. The spectral properties as well as the X-ray diffraction results have revealed that the adsorbed azo dye cations form J-aggregates in the interlayer space. The intercalated azo dyes exhibit reversible trans-to-cis photoisomerization by UV and visible light irradiation.

• 日本粘土学会の論文

著者

• KAKEGAWA NORISHIGE

  Department of Earth and planetary Science, Graduate School of Science, The University of Tokyo

• Ogawa Makoto

  Presto Japan Science And Technology Corporation

• Goto Ryo

  Department Of Earth Sciences Waseda University

• Ogawa Makoto

  Presto Japan Science And Technology Corporation (jst):department Of Earth Sciences Waseda University

• Kakegawa Norishige

  Department Of Earth And Planetary Science Graduate School Of Science The University Of Tokyo

• Kakegawa Norishige

  Department Of Earth Sciences Waseda University

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