4-Acylaminoisoquinolineの接触還元について
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概要
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Catalytic reductions of 4-amino-, 4-acetamido-, and 4-benzamidoisoquinoline under several conditions were examined. Reduction of 4-acetamido- and 4-benzamidoisoquinoline over Adams catalyst in acetic acid or over Raney nickel in ethanol afforded the corresponding 1,2,3,4-tetrahydro derivatives ; whereas their reduction over Adams catalyst in acetic acidsulfuric acid gave the corresponding 5,6,7,8-tetrahydro derivatives. 4-Aminoisoquinoline was reduced to 5,6,7,8-tetrahydro derivative either over Adams catalyst in acetic acid or over Raney nickel in ethanol.
- 公益社団法人日本薬学会の論文
- 1967-05-25
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