大環状ポリアミンによる新たな超分子科学の創造

概要

論文の詳細を見る
Exploitation of saturated macrocyclic polyamines has led to a discovery of numerous novel functions and new molecules such as (1) unique proton sponge properties ; (2) uptake of biological polyanions ; (3) peptide-like metal uptake properties ; (4) stabilization of unusual oxidation states of metal ions (e.g. Cu^<III>, Ni^<III>) ; (5) novel uptake and activation of O_2 by a new Ni^<II>-macrocyclic complex ; (6) a new synthetic pathway to functionalyze polyamines ; (7) the first gold (III) complex that is a new candidate for gold-plating agents ; (8) intrinsic zinc (II) properties pertinent to zinc enzymes ; and (9) selective recognition of thymine by Zn^<II> complexes. These newly discovered properties have created a way to a new type of supramolecular science.
公益社団法人日本薬学会の論文
1996-08-25