Polarography of Anthraquinones and Dianthrones of Rhubarb
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概要
- 論文の詳細を見る
The 1,8-dihydroxyanthraquinones such as emodin (I), physcion (II), crysophanol (III), aloe-emodin (IV) and rhein (V) show reversible 2-electron reduction wave forming the hydroquinones in aqueous isopropanol solutions. Their semiquinones are stable in dimethylformamide. Sennosides (VI) show irreversible 2-electron reduction wave accompanied with 2 adsorption waves, which are ascribed to reductive cleavage of the C-C bridge to the anthrone (VII). The carbonyl in VII is successively reduced to the corresponding alcohol (XI), which seems to dehydrate to the anthracene (XII). Then, the I-V and VI in rhubarb can be determined by polarography.
- 公益社団法人日本薬学会の論文
- 1974-02-25
著者
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朝日 豊
Chemical Research Laboratories, Research and Development Division, Takeda Chemical Industries, Ltd.
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篠崎 一夫
Central Research Division Takeda Chemical Industries Ltd.
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篠崎 一夫
Chemical Research Laboratories, Central Research Division, Takeda Chemical Industries, Ltd.
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三谷 政義
Chemical Research Laboratories, Central Research Division, Takeda Chemical Industries, Ltd.
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大塚 紘司
Chemical Research Laboratories, Central Research Division, Takeda Chemical Industries, Ltd.
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朝日 豊
Chemical Research Laboratories Central Research Division Takeda Chemical Industries Ltd.:(present Ad
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大塚 紘司
Chemical Research Laboratories Central Research Division Takeda Chemical Industries Ltd.
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