Double Bond Migration on the 22(17→28)abeo-Lupane Skeleton
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概要
- 論文の詳細を見る
Double bond migration on the 22(17→28)abeo-lupane skeleton was investigated using 28-p-toluenesulfonyloxy-lupane (4) and its 20(29)-ene derivative (7) as starting materials. In the case of 4,the double bond, formed between C-17 and C-28 after elimination of the p-toluenesulfonyloxy group followed by E-ring expansion, migrated to C-13 and C-18 under acidic conditions. In the case of 7,the double bond, formed after the elimination and the E-ring expansion, migrated in response to migration of the other double bond, 20(29)-ene, under acidic conditions. First, 20(29)-ene migrated to 19-ene (9), and then 17(28)-ene migrated to 13(18)-ene to form a conjugated 13 (18), 19-diene (10). Further migration proceeded to give an equilibrium mixture of 17α-H-11,13(18)-diene (11), 12,17-diene (12) and 17β-H-11,13(18)-diene (13) in a ratio of 3 : 3 : 5.
- 社団法人日本薬学会の論文
- 1994-09-15
著者
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渕野 裕之
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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田中 信壽
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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田中 信壽
東京理科大学薬学部
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渕野 裕之
東京理科大学薬学部
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野澤 修
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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Fuchino Hiroyuki
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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田中 信壽
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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野澤 修
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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