Convenient Synthesis of 2,4-Cyclohexadien-1-ones by Regioselective Methylthiomethylation of Phenols
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概要
- 論文の詳細を見る
A convenient synthesis of a variety of 2,4-cyclohexadien-1-ones 3-7 is described. Reaction of various phenols 2 having appropriate substituents with an excess of S, S-dimethylsuccinmidosulfonium chloride (Corey-Kim reagent, 1)in the presence of triethylamine proceeded with regioselective methylthiomethylation to give methylthiomethyl, bis(methylthiomethyl), or tris(methylthiomethyl)-2,4-cyclohexadien-1-ones 3-7 in satisfactory yields.
- 公益社団法人日本薬学会の論文
- 1993-03-15
著者
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山内 昌茂
Faculty of Pharmaceutical Sciences, Osaka University
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山内 昌茂
城西大学
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渡辺 利郎
Faculty Of Pharmaceutical Sciences Josai University
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山内 昌茂
Faculty Of Pharmaceutical Sciences Josai University
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片山 定
Faculty of Pharmaceutical Sciences, Tokushima University
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片山 定
Faculty Of Pharmaceutical Sciences Josai University
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