α-Chloromaleic Anhydride-Allylcyclohexane Copolymer and Its Dehydrochlorination
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概要
- 論文の詳細を見る
The interaction of α-chloromaleic anhydride (ClMAn) and allylcyclohexane (ACH) was studied. These monomers were found to make a charge-transfer (CT) complex at a 1 : 1 ratio. Copolymerization of ClMAn and ACH in solution gave a white powder in about 50% yield of which analytical data suggested that ClMAn and ACH are copolymerized in a 1 : 1 ratio. By heating the copolymer at 190℃ for 1 h under reduced pressure, dehydrochlorination occurred quantitatively to generate a double bond in the polymer chain at the position of maleic anhydride moiety. The dehydrochlorinated copolymer was found to make a CT complex with acetone but the value of the formation constant was smaller than that of monomeric maleic anhydride.
- 公益社団法人日本薬学会の論文
- 1993-12-15
著者
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佐藤 孝俊
College Of Pharmacy Nihon University
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田口 博之
日本大学薬学部
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小川 尚武
日本大学薬学部
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小川 尚武
College of Pharmacy, Nihon University
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田口 博之
College of Pharmacy, Nihon University
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