BPIMERIZATION OF BENZYLPENICILLOATE IN ALKALINE AQUEOUS SOLUTIONS
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概要
- 論文の詳細を見る
5R, 6R-Benzylpenicilloate (2) epimerized in alkaline equeous solutions to 5S, 6R-benzylpenicilloate (5) via the imine tautomer of benzylpenamaldate (3) rather than the enamine tautomer (4). In the presence of mercury (II) chloride, 2 isomerizes in alkaline aqueous solutions via 4 rather than 3 to afford 5. In both cases, the 5S, 6R-configuration was favored at equilibrium.
- 公益社団法人日本薬学会の論文
- 1985-06-25
著者
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萩中 淳
Faculty Of Pharmaceutical Sciences Mukogawa Women's University
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若居 純子
Faculty Of Pharmaceutical Sciences Mukogawa Women's University
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