Reaktionsmechanismus der Esterbildung aus N-Hydroxysuccinimid und Acylaminosaure mittels Dicyclohexylcarbodiimid
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概要
- 論文の詳細を見る
Es wurde Reaktionsmechanismus, nach welchem sich der Aktivester aus der Acylaminosaure und N-Hydroxysuccinimid mit Dicyclohexylcarbodiimid bildet, mit der ^<18>O markierten Aminosaure untersucht. ^<18>O befindet sich in der Carboxylgruppe des Aktivesters und in dem Dicyclohexylharnstoff. Durch Abspaltung des Hydroxyls der Carboxylgruppe mit Dicyclohexylcarbodiimid wird der Carboxyl-Kohlenstoff aktiviert und bildet mit N-Hydroxysuccinimid den Aktivester.
- 公益社団法人日本薬学会の論文
- 1975-11-25
著者
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川上 猛雄
Isotope Research Laboratory Takeda Chemical Industries Ltd.
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森本 浩
Central Reseach Division Takeda Chemical Industries Ltd.
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森本 浩
Isotope Research Laboratory, Takeda Chemical Industries, Ltd.
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林 伸宜
Isotope Research Laboratory, Takeda Chemical Industries, Ltd.
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林 伸宜
Isotope Research Laboratory Takeda Chemical Industries Ltd.
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