Studies on the Reaction Mechanisms in Heterocyclic Compounds. IV. Ionic Mechanism in the Reaction of Benzoyl Peroxide and Substituted Benzaldehyde (2-Phenyl-3-quinoxalinyl) hydrazone
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概要
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The reaction between benzoyl peroxide and hydrazones follows second-order kinetics, first-order in respect to peroxide and hydrazone. The reaction is accelerated by electron donation groups in hydrazone, and the electronic effect follows Brown-Okamoto's ρσ^+ relationship. Radical inhibitors and polymerizable monomers have no effect. It was concluded that the reaction is not a radical chain process, but involves an ionic process without radical formation, and a possible reaction mechanism is proposed.
- 公益社団法人日本薬学会の論文
- 1969-10-25
著者
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田上 昇一郎
Faculty Of Pharmaceutical Sciences University Of Toyama
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田上 昇一郎
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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志甫 伝逸
Faculty of Pharmaceutical Sciences, University of Toyama
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志甫 伝逸
Faculty Of Pharmaceutical Sciences University Of Toyama
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佐脇 幹夫
Faculty of Pharmaceutical Sciences, University of Toyama
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佐脇 幹夫
Faculty Of Pharmaceutical Sciences University Of Toyama
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