Studies on Azulenes. VII. Oxidation of Hydroazulenes with Selenium Dioxide.

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概要

• 論文の詳細を見る

• On selenium dioxide oxidation, ⊿^9-octahydroazulene gave 1-oxo-⊿^9-octahydroazulene which was converted into 1-methylazulene through Grignard reaction and subsequent dehydrogenation. On similar oxidation, ⊿^<4,9>-hexahydroazulene afforded 4,5-cyclopentatropone (or 6-oxo-⊿^<4,7,9>-tetrahydroazulene) via 6-oxo-⊿^<4,9>-hexahydroazulene. The tropone was identified by its derivation into 6-methylazulene.

• 公益社団法人日本薬学会の論文
• 1957-10-20

著者

• 渡辺 宏

  The Institute For Infectious Diseases

• 渡辺 宏

  Institute for Infectious Diseases, University of Tokyo

関連論文

• Primitive chain network simulations of conformational relaxation for individual molecules in the entangled state (2) Retraction from stretched states (計算機レオロジー特集号)
• Studies on Azulenes. VIII. Troponoids from Azulenogens : Oxidation of Hydroazulenones with Selenium Dioxide.
• Studies on Azulenes. VII. Oxidation of Hydroazulenes with Selenium Dioxide.
• Studies on Azulenes. VI. Synthesis of Azulenes from Hydrindeneglycol Diacetate without Dehydrogenation.
• Studies on Azulenes. V. S-Guaiazulene-3-sulfonic Acid.
• アズレン類の研究(第2報)ポリブロムアズレン類の合成

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