立体化学の研究(第9報)dl-フェニルセリノール類 : その新合成法と立体化学的推察
スポンサーリンク
概要
- 論文の詳細を見る
In the derivation of dl-1-phenyl-2-acylamino-1,3-dibromopropanes to dl-phenyl-serinols, the stepwise displacement of bromine atoms by hydroxyl groups was examined in connection with earlier conclusions. It was found that the proximity of acyl group to the displacement centre favored the internal Sn_2 and that its distance from the neighborhood favored Sn_1 in the solvolytic condition.
- 公益社団法人日本薬学会の論文
- 1956-04-20
著者
-
友枝 宗光
Eisai Co., Ltd.
-
友枝 宗光
Eisai Co. Ltd.
-
田口 胤三
Pharmaceutical Institute, Medical Faculty, University of Kyushu
-
友枝 宗光
Pharmaceutical Institute, Medical Faculty, University of Kyushu
-
田口 胤三
Pharmaceutical Institute Medical Faculty University Of Kyushu
-
福山 東樹
Pharmaceutical Institute, Medical Faculty, University of Kyushu
-
福山 東樹
Pharmaceutical Institute Medical Faculty University Of Kyushu
関連論文
- Studies on Conformation and Reactivity. VI. The Reduction Reaction of Cholesta-3,5-dieno [3,4-b] oxathiane with Lithium in Liquid Ammonia. The Characterization of Unique Ultraviolet Absorption of the 3,5-Dieno [3,4-b] oxathiano System
- The Polyphosphoric Acid-Catalyzed Ring Opening of 4,5-Epoxy-3-oxo Steroids. IV. The Synthesis of 17α-Hydroxy-4-ethylthiopregn-4-ene-3,20-dione and Its Analogs
- Synthesis of Bisfurazanobenzo-2,1,3-thiadiazole and Related Compounds
- Synthesis and Reaction of Furazanobenzothiadiazole and Related Compounds
- Studies on Conformation and Reactivity. II. The Polyphosphoric Acid-catalyzed Ring Opening of 4,5-Epoxy-3-oxo Steroids. 2. The Synthesis of 4-Ethylthio-17β-acetoxyandrost-4-en-3-one and its Analogs.
- Some Homolytic Reaction Behaviors of Diethyl Azodicarboxylate
- Studies on Conformation and Reactivity. III. The Polyphosphoric Acid-catalyzed Ring Opening of 4,5-Epoxy-3-oxo Steroids. 3. The Synthesis of 16α, 17-Epoxy-4-ethyl-thiopregn-4-ene-3,20-dione and its Analogs
- Studies in Stereochemistry. XII. Mechanism of Racemization in Schiff Bases of D-Methionine Ethyl Ester.
- Studies in Stereochemistry. XIII. dl-Phenylserinols : A New Synthesis and its Stereochemical Findings. (5)
- The Formation and Chemical Properties of Diastereomeric 1,2-Dimethyl-3-phenylaziridine
- 立体化学の研究(第6報)dl-しs-2-Benzoylaminocyclohexyl Tosylate の Solvolysis
- 立体化学の研究(第4報)アルカノールアミン(4)dl-Regular-2,5-Diphenyl-4-methyloxazoline : その生成とMethyl Tosylateの作用
- Studies in Stereochemistry. I. : Alkanolamines. (1). : Action of Methylating Agents on dl-trans-2,5-Diphenyl-4-methyloxazoline.
- Thermal Behavior of dl-trans-2-Iodo-N, N-dimethylcyclohexylamine involving a New Rearrangement. The Formation of Cyclopentylmethanal and Cyclohexanone.
- 立体化学の研究(第11報)dl-フェニルセリノール類 : その新合成法と立体化学的知見(4)dl-threo-2-Phenyl-4-phenylhydroxymethyl-⊿^2-oxazolineのAcOK-Ac_2O処理に於ける酢酸の影響
- 立体化学の研究(第10報)dl-フェニルセリノール類 : その新合成法と立体化学的知見(3)塩基性媒剤に於けるdl-threo-2-Phenyl-4-phenylhydroxymethyl-⊿^2-oxazolineの開環
- 立体化学の研究(第9報)dl-フェニルセリノール類 : その新合成法と立体化学的推察
- タロラムフェニコールの一新合成法及び立体化学的発見
- Physicochemical Interaction of the Carcinogen 4-Nitroquinoline 1-Oxide and Its Analogues with Purine and Pyrimidine Bases as the Component of Nucleic Acid
- Studies on Conformation and Reactivity. VIII. Stereochemical Aspects of the Diels-Alder Reaction of Diethyl Azodicarboxylate with Steroid Homodienes. (1)
- An Approach to the Synthesis of New Steroidal Heterocycles with a Diaza-function
- Studies in Stereochemistry. XX. dl-Phenylserinols : A New Synthesis and its Stereochemical Findings. (7). An Isomerization of dlthreo-2-Phenyl-4-α-hydroxybenzyl-2-oxazoline to dl-threo-4-Hydroxymethyl-2,5-diphenyl-2-oxazoline in Basic Media : The Correcti
- Studies in Stereochemistry. XIV. dl-Phenylserinols : A New Synthesis and its Stereochemical Findings. (6). A Synthesis of dl-threo-2-Benzamido-1-p-nitrophenyl-1,3-propanediol from trans-p-Nitrocinnamyl Alcohol.
- 1-Methyl-5,6,7,8-tetrahydronaphthaleneの合成とニトロ化について