Benzylamine誘導体の分解(第5報)ベンチルカチオンの芳香性置換反応について その2

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概要

• 論文の詳細を見る

• 1) The reaction between p-X-C_6H_4-CH_2OH (X=substituent with +M effect) and p-Y-C_6H_5 (Y=substituent with +M effect) in acid was examined and it was found that products formed in the case of X=CH_3O were mainly [chemical formula] and [chemical formula], while in the case of X=(CH_3)_2N and H_2N, [chemical formula] is chiefly formed. 2) p-Methoxybenzyl alcohol undergoes aromatic electrophilic substitution with [chemical formula] and hydrochloric acid. 3) The reaction mechanism whereby diphenylmethane is formed by the aromatic electrophilic substitution of [chemical formula] has been clarified.

• 公益社団法人日本薬学会の論文
• 1955-04-20

著者

• 砂川 玄俊

  Takamine Research Laboratory Sankyo Co. Ltd.

関連論文

• Studies on Seven-membered Ring Compounds. VIII. Syntheses of 5-Nitrosotropolone Derivatives.
• Studies on the Total Synthesis of dl-Colchiceine. II. Synthesis of dl-Demethoxydeoxyhexahydrocolchiceine.
• Synthesis of Colchicine Synthesis of dl-Demethoxydeoxy-hexahydrocolchicine
• Benzylamine誘導体の分解(第3報)
• Benzylamine誘導体の分解(第5報)ベンチルカチオンの芳香性置換反応について その2
• Benzylamine誘導体の分解(第4報)ベンチルカチオンの芳香性置換反応について その1

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