Benzylamine誘導体の分解(第4報)ベンチルカチオンの芳香性置換反応について その1

スポンサーリンク

概要

• 論文の詳細を見る

• The compounds of the general formula [chemical formula], where R is a substituent with +M effect in the ortho- or para-position of -CH_2-, R' is H or alky l (or aminoalkyl) group, and R" is an aromatic residue, when heated with dilute hydrochloric acid, are cleaved first into benzyl alcohol and an aromatic amine. When the reaction proceeds further, a diphenylmethane compounds are formed by the aromatic electrophilic substitution of the following order : [chemical formula] In some cases, the aromatic amine liberated in the first stage of the reaction takes part in the second stage of the reaction which proceeds in the following order, as had earlier been recognized.

• 公益社団法人日本薬学会の論文
• 1955-04-20

著者

• 砂川 玄俊

  Takamine Research Laboratory Sankyo Co. Ltd.

関連論文

• Studies on Seven-membered Ring Compounds. VIII. Syntheses of 5-Nitrosotropolone Derivatives.
• Studies on the Total Synthesis of dl-Colchiceine. II. Synthesis of dl-Demethoxydeoxyhexahydrocolchiceine.
• Synthesis of Colchicine Synthesis of dl-Demethoxydeoxy-hexahydrocolchicine
• Benzylamine誘導体の分解(第3報)
• Benzylamine誘導体の分解(第5報)ベンチルカチオンの芳香性置換反応について その2
• Benzylamine誘導体の分解(第4報)ベンチルカチオンの芳香性置換反応について その1

スポンサーリンク