Synthesis of 1-Hydroxybicyclo[3.2.1]oct-3-en-2-ones by Acyloin Rearrangement of 1-Methoxy- or 1-tert-Butyldimethylsilyloxy-bicyclo[2.2.2]oct-5-en-2-ones

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概要

• 論文の詳細を見る

• 1-Hydroxy- or 1,8-dihydroxy-bicyclo[3.2.1]oct-3-en-2-ones were obtained from 1-methoxy- or 1-tert-butyldimethylsilyloxy-bicyclo[2.2.2]oct-5-en-2-ones via successive processes involving demethylation or desilylation and acyloin rearrangement by reaction with acids or tetra-n-butylammonium fluoride (TBAF).

• 公益社団法人日本薬学会の論文
• 1997-09-15

著者

• Aoe K

  Tanabe Seiyaku Co. Ltd. Osaka

• HIRAMATSU Hajime

  Analytical Research Laboratory, Tanabe Seiyaku Co. Ltd.

• Yamauchi Masashige

  Faculty Of Pharmaceutical Science Josai University

• KATAYAMA Sadamu

  Faculty of Pharmaceutical Sciences, Josai University

• AOE Keiichi

  Analytical Research Laboratory, Tanabe Seiyaku Co., Ltd.,

• Hiramatsu Hajime

  Analytical Research Laboratory Tanabe Seiyaku Co. Ltd.

• Katayama S

  Faculty Of Pharmaceutical Sciences Josai University

• Katayama Sadamu

  Faculty Of Pharmaceutical Sciences Josai University

関連論文

• Crystal Structures of Diastereomeric 1 : 1 Complexes of (R)- and (S)-Phenylalanine (S)-Mandelic Acid
• Diastereoselective synthesis of 2-alkylated 4-silyloxyprolineesters
• The Influence of Ligand Side Chain on the Enantioselectivity of Lewis Acid Catalyzed Diels-Alder Reactions
• Synthesis of 1-Hydroxybicyclo[3.2.1]oct-3-en-2-ones by Acyloin Rearrangement of 1-Methoxy- or 1-tert-Butyldimethylsilyloxy-bicyclo[2.2.2]oct-5-en-2-ones
• Reactivity of 2-Methylene-1, 3-dicarbonyl Compounds. 1, 3-Dipolar Cycloaddition Reaction with Ethyl Diazoacetate
• Base-promoted Acyloin Rearrangement of 1,8-Di-tert-butyldimethylsilyl-oxybicyclo[2.2.2]oct-5-en-2-ones
• Photochemical Synthesis of Bicyclo[4.1.0]hept-2-enes

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