Base-promoted Acyloin Rearrangement of 1,8-Di-tert-butyldimethylsilyl-oxybicyclo[2.2.2]oct-5-en-2-ones

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概要

• 論文の詳細を見る

• Treatment of 1,8-di-tert-butyldimethylsilyloxybicyclo[2.2.2]oct-5-en-2-ones having an electron-withdrawing group such as a nitro, formyl, cyano, and imido group at C-7 with a strong base (potassium hydride, or potassium bistrimethylsilylamide, etc.), resulted in an acyloin rearrangement reaction accompanied by retention of two silyloxy groups to afford 1,8-disilyloxybicyclo[3.2.1]oct-3-en-2-ones.

• 公益社団法人日本薬学会の論文
• 2005-06-01

著者

• Yamauchi Masashige

  Faculty Of Pharmaceutical Science Josai University

• KATAYAMA Sadamu

  Faculty of Pharmaceutical Sciences, Josai University

• Katayama Sadamu

  Faculty Of Pharmaceutical Sciences Josai University

関連論文

• Diastereoselective synthesis of 2-alkylated 4-silyloxyprolineesters
• The Influence of Ligand Side Chain on the Enantioselectivity of Lewis Acid Catalyzed Diels-Alder Reactions
• Synthesis of 1-Hydroxybicyclo[3.2.1]oct-3-en-2-ones by Acyloin Rearrangement of 1-Methoxy- or 1-tert-Butyldimethylsilyloxy-bicyclo[2.2.2]oct-5-en-2-ones
• Reactivity of 2-Methylene-1, 3-dicarbonyl Compounds. 1, 3-Dipolar Cycloaddition Reaction with Ethyl Diazoacetate
• Base-promoted Acyloin Rearrangement of 1,8-Di-tert-butyldimethylsilyl-oxybicyclo[2.2.2]oct-5-en-2-ones
• Photochemical Synthesis of Bicyclo[4.1.0]hept-2-enes

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