Stereoselective Radical Addition to α-Methylenebutyrolactones by Indirect Electroreduction Catalyzed by a Nickel(II) Complex
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概要
- 論文の詳細を見る
The addition of butyl radicals to β- and/or γ-disubstituted α-methylenebutyrolactones by a nickel(II) complex-catalyzed indirect electroreduction using equimolar amounts of butyl iodides and α-methylenebutyrolactones provides cis-(C-α) : (C-β)-trisubstituted lactones as the major product. The addition was successful because the present method to permits long lifetimes for the initial butyl radicals and decreases lifetimes of the final adduct radicals by selective reduction of these radicals.
- 公益社団法人日本薬学会の論文
- 1997-01-15
著者
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Matsui Eiki
Faculty Of Pharmaceutical Sciences Osaka University
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Matsui E
Faculty Of Pharmaceutical Sciences Osaka University
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Ozaki S
Faculty Of Pharmaceutical Sciences Osaka University
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Ozaki Shigeko
Faculty Of Pharmaceutical Sciences Osaka University
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Ohmori Hidenobu
Faculty Of Pharmaceutical Sciences Osaka University
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Mitsui Eiki
Faculty of Pharmaceutical Sciences, Osaka University
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