SUS347鋼の高温高圧純水中の応力腐食割れにおけるNbの役割

概要

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Role of Niobium on stress corrosion cracking (SCC) of SUS347 stainless steel was investigated in high temperature water at 562K. SCC test was carried out using a slow strain rate testing technique (SSRT) in dissslved oxygen of 8 ppm. The precipitation behavior of NbC and M_<23>C_6 was evaluated by transmission electron microscopy and intergranular corrosion test. All the specimens were firstly stabilized at 1173K for 3.6ks, in order to precipitate more NbC in the specimen. The specimen was solutionized at 1273K to 1573K for 1.8ks, and then sensitized at 923K for 72ks. The solution-treated specimen up to 1273K occured general corrosion and had low pitting potential, and SCC in the high temperature water hardly occured, because of the presence of NbC. The amount of NbC decreased with increasing solution treatment temperature in the range of 1473 K to 1573K. M_<23>C_6 precipitated at the grain boundary, and intergranular corrosion occured by the sensitization treatment at 923K. The intergranular stress corrosion cracking (IGSCC) occured in the range above 1473K, because of the precipitation of M_<23>C_6 at the grain boundary.
社団法人溶接学会の論文
1990-08-05